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6088-88-6 - 2-Butenylmagnesium chloride, 0.5M in MeTHF - H51171 - Alfa Aesar

H51171 2-Butenylmagnesium chloride, 0.5M in MeTHF

CAS-Nummer
6088-88-6
Synonyme

Größe Preis ($) Menge Verfügbarkeit
50ml 165,00
100ml 264,00
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2-Butenylmagnesium chloride, 0.5M in MeTHF

MDL
MFCD01321226

Chemische Eigenschaften

Formel
C4H7ClMg
Molmasse
114.86
Sensitivität
Air & Moisture Sensitive
Löslichkeit
It reacts violently with water.

Anwendungen

2-Butenylmagnesium chloride is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Bemerkungen

Air & moisture sensitive. Incompatible with oxidizing agents and bases.

Literaturverweise

Giuseppe Bartoli; Enrico Marcantoni; Marino Petrini; Renato Dalpozzo. Reaction of aryl and alkyl nitro compounds with 2-butenylmagnesium chloride: synthesis of a new class of nitrones. J. Org. Chem. 1990, 55, (14),4456-4459

 

Motokazu Uemura; Tatsuya Minami; Kazuo Isobe; Toshio Kobayashi; Yuji Hayashi. Diastereoselective addition of 2-butenylmetal “ate” complexes to aromatic ketones mediated by Cr (CO)3 complexation. Tetrahedron Letters. 1986, 27, (8),967-970

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H261-H313-H314-H318

Highly flammable liquid and vapour. In contact with water releases flammable gas. May be harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
4.3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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