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As lysine residue its 3-amino group is often used for carrying a tag moiety such as a fluorescent dye, a quencher or biotin.
Tooru Kimura, et al. Design and synthesis of highly active Alzheimers β-secretase (BACE1) inhibitors, KMI-420 and KMI-429, with enhanced chemical stability.Bioorg. Med. Chem. Lett.,2005,15(3), 211-215.
Yosup Rew, et al. Total Synthesis and Examination of Three Key Analogues of Ramoplanin: A Lipoglycodepsipeptide with Potent Antibiotic Activity.J. Am. Chem. Soc.,2014,126(4), 1041-1043.