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(S)-3-(Boc-amino)-5-methylhexanoic acid is used as building blocks for the synthesis of "carba peptides" and building block for β-peptides.
Daniel H.Rich; Byung Jo Moon; Amrit S.Boparai. Synthesis of (2S,3R)-3-amino-2-hydroxy-5-methylhexanoic acid derivatives. Application to the synthesis of amastatin, an inhibitor of aminopeptidases. J. Org. Chem. 1980, 45, (12),2288-2290