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192182-54-0 - 3,5-Dimethoxybenzeneboronic acid, 98% - H52965 - Alfa Aesar

H52965 3,5-Dimethoxybenzeneboronic acid, 98%

CAS-Nummer
192182-54-0
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 43,70
5g 166,00
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3,5-Dimethoxybenzeneboronic acid, 98%

MDL
MFCD03095127

Chemische Eigenschaften

Formel
C8H11BO4
Molmasse
181.98
Schmelzpunkt
205-207°
Löslichkeit
Soluble in methanol.

Anwendungen

3,5-Dimethoxybenzeneboronic acid is used as reactant for palladium-catalyzed coupling reactions, preparation of benzopyranone derivatives as positive GABAA receptor modulators, preparation of aryl alkenes via three-component coupling catalyzed by palladium and Suzuki-Miyaura coupling. It is also used as reactant for rhodium catalyzed cyanation with N-cyano-N-phenyl-p-methylbenzenesulfonamide and preparation of bisphosphonate inhibitors of human farnesyl pyrophosphate synthase.

Bemerkungen

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literaturverweise

John Kallikat Augustine; Agnes Bombrun; Padma Alagarsamy; Anandh Jothi. Selective synthesis of 5,6-dihydrophenanthridines, 5,6-dihydrobenzo[c][1,8]naphthyridines and their fully aromatized analogues via the Pictet-Spengler reaction mediated by peptide coupling agent propylphosphonic anhydride (T3P). Tetrahedron Letters. 2012, 53, (46),6280-6287

 

Francesco Tramutola; Lucia Chiummiento; Maria Funicello; Paolo Lupattelli. Practical and efficient ipso-iodination of arylboronic acids via KF/I2 system. Tetrahedron Letters. 2015, 56, (9),1122-1123

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2931.90
TSCA
No

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