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127972-00-3 - 2-Methoxy-5-methylbenzeneboronic acid, 95% - H53059 - Alfa Aesar

H53059 2-Methoxy-5-methylbenzeneboronic acid, 95%

CAS-Nummer
127972-00-3
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 34,08
5g 128,20
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2-Methoxy-5-methylbenzeneboronic acid, 95%

MDL
MFCD02179465

Chemische Eigenschaften

Formel
C8H11BO3
Molmasse
165.99
Schmelzpunkt
80-84°
Löslichkeit
Soluble in methanol.

Anwendungen

Reactant for coupling reactions, Preparation of selective quinazolinyl-phenol inhibitors of CHK1 as potential antitumors and radioprotectants, Rh-catalyzed asymmetric arylation of aldehydes, Stereoselective hydroarylation reactions, Suzuki-Miyaura cross-coupling.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literaturverweise

Smita Rausaria et. al. Manganese(III) complexes of bis(hydroxyphenyl)dipyrromethenes are potent orally active peroxynitrite scavengers. Journal of the American Chemical Society. 2011 , 133(12), 4200-4203 .

Nishimura, T.; et al. The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes . Chem. Commun. (Camb.)2009, 5713-5715.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2931.90
TSCA
No
RTECS
Y

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