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77758-51-1 - Methyl 5-hexynoate, 97% - 5-Hexynoic acid methyl ester - H53370 - Alfa Aesar

H53370 Methyl 5-hexynoate, 97%

CAS-Nummer
77758-51-1
Synonyme
5-Hexynoic acid methyl ester

Größe Preis ($) Menge Verfügbarkeit
5g 71,07
25g 273,98
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Methyl 5-hexynoate, 97%

MDL
MFCD00671366

Chemische Eigenschaften

Formel
C7H10O2
Molmasse
126.16
Siedepunkt
60-62°/10mm
Brechungsindex
1.434

Anwendungen

Methyl 5-hexynoate is used in the synthesis of methyl (Z)-8-chlorooct-7-ene-5-ynoate with (Z)-1,2-dichloro-ethane.

Bemerkungen

Incompatible with oxidizing agents.

Literaturverweise

Tang, X.; Huang, X.; Cao, T.; Han, Y.; Jiang, X.; Lin, W.; Tang, Y.; Zhang, J.; Yu, Q.; Fu, C. CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes. Org. Chem. Front. 2015, 2 (6), 688-691.

Gong, J. X.; Wang, H. Y.; He, W. F.; Wang, Z. Z.; Xiao, W.; Guo, Y. W. A concise synthesis of xestospongic acid methyl ester with pancreatic lipase inhibitory activity. J. Asian Nat. Prod. Res. 2013, 15 (8), 916-919.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2916.19
TSCA
No

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