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Methyl 5-hexynoate is used in the synthesis of methyl (Z)-8-chlorooct-7-ene-5-ynoate with (Z)-1,2-dichloro-ethane.
Tang, X.; Huang, X.; Cao, T.; Han, Y.; Jiang, X.; Lin, W.; Tang, Y.; Zhang, J.; Yu, Q.; Fu, C. CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes. Org. Chem. Front. 2015, 2 (6), 688-691.
Gong, J. X.; Wang, H. Y.; He, W. F.; Wang, Z. Z.; Xiao, W.; Guo, Y. W. A concise synthesis of xestospongic acid methyl ester with pancreatic lipase inhibitory activity. J. Asian Nat. Prod. Res. 2013, 15 (8), 916-919.
Gefahrenhinweise (EU): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.