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18163-47-8 - 1-Iodo-2-(trimethylsilyl)acetylene, 97% - H53375 - Alfa Aesar

H53375 1-Iodo-2-(trimethylsilyl)acetylene, 97%

CAS-Nummer
18163-47-8
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 27,50
5g 103,00
25g 409,00
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1-Iodo-2-(trimethylsilyl)acetylene, 97%

MDL
MFCD00274201

Chemische Eigenschaften

Formel
C5H9ISi
Molmasse
224.12
Siedepunkt
130°
Flammpunkt
48°(118°F)
Dichte
1.46
Brechungsindex
1.5110
Sensitivität
Light Sensitive

Anwendungen

1-Iodo-2-(trimethylsilyl)acetylene may be used to investigate the reactivity of diamagnetic cobalt(I) complex, Tol-BDI((2-pp)2)Co [Tol-BDI((2-pp)2)H = 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine]. It may be used for the synthesis of 1-(4-trimethylsilanylbuta-1,3-diynyl)pyrene, via Pd-coupling with 1-iodo-2-trimethylsilylacetylene.

Bemerkungen

Light sensitive. Incompatible with oxidizing agents.

Literaturverweise

Lunhan Ding; Susan V.Olesik. Synthesis of polymer nanospheres and carbon nanospheres using the monomer 1,8-dihydroxymethyl-1,3,5,7- octatetrayne. Nano Letters. 2004, 4, (11),2271-2276

 

Elodie E.Marlier; Bridget A.Ulrich; Kristopher McNeill. Synthesis and reactivity of an isolable cobalt(I) complex containing a β-diketiminate-based acyclic tetradentate ligand. Inorg. Chem. 2012, 51, (4),2079-2085

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H334-H317-H361-H226-H302-H312-H332

May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of damaging fertility or the unborn child. Flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled.

Sicherheitshinweise: P210-P285-P201-P261-P280-P281-P303+P361+P353-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. In case of inadequate ventilation wear respiratory protection. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
3
Verpackungsgruppe
III
Harmonized Tariff Code
2931.90
TSCA
No

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