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592-46-1 - 2,4-Hexadiene, tech. 90%, mixture of isomers - H53404 - Alfa Aesar

H53404 2,4-Hexadiene, tech. 90%, mixture of isomers

CAS-Nummer
592-46-1
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 25,50
5g 94,70
25g 378,00
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2,4-Hexadiene, tech. 90%, mixture of isomers

MDL
MFCD00009297
EINECS
209-757-3

Chemische Eigenschaften

Formel
C6H10
Molmasse
82.15
Siedepunkt
82°
Flammpunkt
-14°(-7°F)
Dichte
0.72
Brechungsindex
1.445
Löslichkeit
Miscible with ethanol, ethyl ether and chloroform. Immiscible with water.

Anwendungen

2,4-Hexadiene is used in the production of 3,6-dimethyl-3,6-dihydro-[1,2]dithiine.

Bemerkungen

Incompatible with strong oxidizing agents.

Literaturverweise

Geary, L. M.; Glasspoole, B. W.; Kim, M. M.; Krische, M. J. Successive C-C Coupling of Dienes to Vicinally Dioxygenated Hydrocarbons: Ruthenium Catalyzed [4 + 2] Cycloaddition across the Diol, Hydroxycarbonyl, or Dione Oxidation Levels. J. Am. Chem. Soc. 2013, 135 (10), 3796-3799.

Liu, B.; Li, K-N.; Luo, S-W.; Huang, J-Z.; Pang, H.; Gong, L-Z. Chiral Gold Complex-Catalyzed Hetero-Diels-Alder Reaction of Diazenes: Highly Enantioselective and General for Dienes. J. Am. Chem. Soc. 2013, 135 (9), 3323-3326.

Polyak, I.; Boulanger, E.; Sena, K.; Thiel, W. A microiterative intrinsic reaction coordinate method for large QM/MM systems. Phys. Chem. Chem. Phys. 2013, 15 (34), 14188-14195.

Lyons, T. W; Guironnet, D.; Findlater, M.; Brookhart, M. Synthesis of p-Xylene from Ethylene. J. Am. Chem. Soc. 2012, 134 (38), 15708-15711.

Bérard, S.; Valee, C.; Delcroix, D. Sorbic Acid as a Renewable Resource for Atom-Economic and Selective Production of p-Toluic Acid and Alkyl-p-Toluates: Intermediates to Bioterephthalic Acid and Esters. Ind. Eng. Chem. Res. 2015, 54 (28), 7164-7168.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2901.29
TSCA
No

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