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13139-86-1 - 4-Methoxyphenylmagnesium bromide, 1.0 M in 2-MeTHF - H54317 - Alfa Aesar

H54317 4-Methoxyphenylmagnesium bromide, 1.0 M in 2-MeTHF

CAS-Nummer
13139-86-1
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100ml 45,50
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4-Methoxyphenylmagnesium bromide, 1.0 M in 2-MeTHF

MDL
MFCD00013515

Chemische Eigenschaften

Formel
C7H7BrMgO
Molmasse
211.34
Sensitivität
Air & Moisture Sensitive
Löslichkeit
It reacts with water.

Anwendungen

4-Methoxyphenylmagnesium bromide is applied in Grignard-reactions as a reagent for the introduction of the 4-methoxyphenyl group.

Bemerkungen

Air and moisture sensitive. Incompatible with oxidizing agents and acids.

Literaturverweise

Takafumi Yamagami; Ryo Shintani; Eiji Shirakawa; Tamio Hayashi. Iron-catalyzed arylmagnesiation of aryl(alkyl)acetylenes in the presence of an N-Heterocyclic carbene ligand. Org. Lett. 2007, 9,(6), 1045-1048.

 

N.C.Deno; J.J.Jaruzelski; Alan Schriesheim. Carbonium ions. I. An acidity function (C0) derived from arylcarbonium ion equilibria1. J. Am. Chem. Soc. 1955, 77,(11), 3044-3051.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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