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66065-85-8 - N-(2,2,2-Trichloroethoxycarbonyloxy)succinimide, 98+% - N-Succinimidyl 2,2,2-trichloroethyl carbonate - H54616 - Alfa Aesar

H54616 N-(2,2,2-Trichloroethoxycarbonyloxy)succinimide, 98+%

CAS-Nummer
66065-85-8
Synonyme
N-Succinimidyl 2,2,2-trichloroethyl carbonate

Größe Preis ($) Menge Verfügbarkeit
1g 11,10
5g 44,70
25g 185,00
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N-(2,2,2-Trichloroethoxycarbonyloxy)succinimide, 98+%

MDL
MFCD00075216

Chemische Eigenschaften

Formel
C7H6Cl3NO5
Molmasse
290.49
Schmelzpunkt
111-113°
Sensitivität
Moisture Sensitive
Löslichkeit
Soluble in dioxane, THF, DMF, CH2Cl2, alcohols, and most common organic solvents.

Anwendungen

N-(2,2,2-Trichloroethoxycarbonyloxy)succinimide was used in the synthesis of methyl [phenyl 5-(2,2,2-trichloroethoxycarbonylamino)-3,5-dideoxy-2-thio-β-D-glycero-D-galacto-2-nonulopyranosid]-onate; and phenyl 3,4-di-O-benzyl-6-O-(tert-butyl-dimethyl-silyl)-1-selanyl-2-(2,2,2-trichloroethoxycarbonylamine)-β-D-galactopyranoside.

Bemerkungen

Moisture sensitive. Incompatible with oxidizing agents and heat.

Literaturverweise

Chien-Tai Ren; Chien-Sheng Chen; Shih-Hsiung Wu. Synthesis of a sialic acid dimer derivative, 2'alpha-O-benzyl Neu5Ac-alph-(2-->5)Neu5Gc. Journal of Organic Chemistry. 2002, 67,(4), 1376-1379.

 

Chien-Tai Ren; Yu-Hsuan Tsai; Yu-Liang Yang; Wei Zou; Shih-Hsiung Wu. Synthesis of a tetrasaccharide glycosyl glycerol. Precursor to glycolipids of Meiothermus taiwanensis ATCC BAA-400. Journal of Organic Chemistry. 2007, 72,(14), 5427-5430.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H311-H332-H319-H335

Toxic if swallowed. Toxic in contact with skin. Harmful if inhaled. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P301+P310-P305+P351+P338-P361-P304+P340-P312-P363-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2925.19
TSCA
No

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