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89980-69-8 - 3,4-Dimethoxyphenylmagnesium bromide, 0.5M in THF - H54654 - Alfa Aesar

H54654 3,4-Dimethoxyphenylmagnesium bromide, 0.5M in THF

CAS-Nummer
89980-69-8
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100ml 253,38
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3,4-Dimethoxyphenylmagnesium bromide, 0.5M in THF

MDL
MFCD01311476

Chemische Eigenschaften

Formel
C8H9BrMgO2
Molmasse
241.37
Sensitivität
Air & Moisture Sensitive
Löslichkeit
Reacts with water.

Anwendungen

Used as a pharmaceutical intermediate.

Bemerkungen

Air and moisture sensitive. Air, oxidizing agents, heat are incompatible. Store under cool place.

Literaturverweise

E. J. Corey.; Raman K. Bakshi. ; Saizo Shibata.; Chung Pin Chen.; Vinod K. Singh. A stable and easily prepared catalyst for the enantioselective reduction of ketones. Applications to multistep syntheses. J. Am. Chem. Soc. 1987, 109 (25),7925-7926.

Margaretha Van der Mey.; Armin Hatzelmann.; Ivonne J. Van der Laan.; Geert J. Sterk.; Ulrich Thibaut.; Hendrik Timmerman. Novel Selective PDE4 Inhibitors. 1. Synthesis, Structure-Activity Relationships, and Molecular Modeling of 4-(3,4-Dimethoxyphenyl)-2H-phthalazin-1-ones and Analogues. J. Med. Chem. 2001, 44 (16),2511-2522.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H314-H351-H335

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Suspected of causing cancer. May cause respiratory irritation.

Sicherheitshinweise: P210-P260-P201-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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    3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

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