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185416-17-5 - 3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF - H54781 - Alfa Aesar

H54781 3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

CAS-Nummer
185416-17-5
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100ml 276,00
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3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

MDL
MFCD13319917

Chemische Eigenschaften

Formel
C9H11BrMgO
Molmasse
239.39
Sensitivität
Air & Moisture Sensitive
Löslichkeit
Reacts with water.

Anwendungen

3,5-Dimethyl-4-methoxyphenylmagnesium bromide is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff fields.

Bemerkungen

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents and bases. It is sensitive to air and moisture. Protect from humidity and water. Store under dry inert gas.

Literaturverweise

Tamio Hayashi.; Mitsuo Ishigedani. Rhodium-catalyzed asymmetric arylation of α,β-unsaturated imines with arylstannanes. Catalytic asymmetric synthesis of allylic amines. Tetrahedron. 2001, 57 (13), 2589-2595.

Jin Wook Han.; Tamio Hayashi. Enhanced catalytic activity in asymmetric hydrosilylation of 1,3-dienes with a soluble palladium catalyst. Tetrahedron: Asymmetry. 2002, 13 (3), 325-331.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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    3,4-Dimethoxyphenylmagnesium bromide, 0.5M in THF

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