Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

920-39-8 - Isopropylmagnesium bromide, 3M in 2-MeTHF - H54840 - Alfa Aesar

H54840 Isopropylmagnesium bromide, 3M in 2-MeTHF

CAS-Nummer
920-39-8
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100ml 85,70
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Isopropylmagnesium bromide, 3M in 2-MeTHF

MDL
MFCD00672110

Chemische Eigenschaften

Formel
C3H7BrMg
Molmasse
147.30
Sensitivität
Air & Moisture Sensitive
Löslichkeit
Miscible with tetrahydorfuran and diethyl ether. Immiscible with hydrocarbons.

Anwendungen

Isopropylmagnesium bromide is a Grignard reagent used in organic synthesis, especially for the introduction of iso-propyl group to carbonyl compounds. It is also used as a strong base in aprotic solvent.

Bemerkungen

Air and moisture sensitive. Incompatible with strong bases, strong oxidizing agents and strong acids.

Literaturverweise

Du, B. X.; Quan, Z. J.; Da, Y. X.; Zhang, Z.; Wang, X. C. Chemo-Controlled Cross-Coupling of Di(hetero)aryl Disulfides with Grignard Reagents: C-C vs. C-S Bond Formation. Adv. Synth. Catal. 2015, 357 (6), 1270-1276.

Roy, A.; Bhat, B. A.; Lepore, S. D. Organo-Manganese η2-Auxiliary Directed Reactions: A Diastereoselective Approach to 2, 3-Allenols. Org. Lett. 2015, 17 (4), 900-903.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H261-H314-H318

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
4.3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
Yes

Empfohlen

  • A10173

    Trifluoromethanesulfonic acid, 98+%
  • A11716

    Diethylamine, 99+%
  • H51155

    Isopropylmagnesium chloride, 1M in MeTHF
  • H51156

    Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF
  • 32958

    Cadmium bromide tetrahydrate, Reagent Grade

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf