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1643-73-8 - 4-Fluorobenzylmagnesium chloride, 0.50M in 2-MeTHF - H54990 - Alfa Aesar

H54990 4-Fluorobenzylmagnesium chloride, 0.50M in 2-MeTHF

CAS-Nummer
1643-73-8
Synonyme

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4-Fluorobenzylmagnesium chloride, 0.50M in 2-MeTHF

MDL
MFCD01319898

Chemische Eigenschaften

Formel
C7H6ClFMg
Molmasse
168.88
Sensitivität
Air & Moisture Sensitive
Löslichkeit
Reacts with water.

Anwendungen

4-Fluorobenzylmagnesium chloride is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff fields.

Bemerkungen

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents and bases. It is sensitive to air and moisture. Protect from humidity and water. Store under dry inert gas.

Literaturverweise

Brian T. Gregg.; Kathryn C. Golden.; John F. Quinn.; Hong-Jun Wang.; Wei Zhang.; Ruifang Wang.; Francis Wekesa.; Dmytro O. Tymoshenko. Rapid, one-pot synthesis of α,α-disubstituted primary amines by the addition of Grignard reagents to nitriles under microwave heating conditions. Chemical Communications. 2009, 50 (27), 3978-3981.

Gang Wu.; Zhen-Wei Cai.; Mark S. Bednarz.; Octavian R. Kocy.; Ashvinikumar V. Gavai.; Jollie D. Godfrey.; William N. Washburn .; Michael A. Poss.; Philip M. Sher. Addition of Benzylic and Allylic Organozinc and Grignard Reagents to Resin-Bound Imines To Provide α-Branched Secondary Amines Bearing a Wide Variety of Functional Groups. Utility in the Synthesis of β-3 Adrenergic Receptor Agonists. J. Comb. Chem. 2005, 7 (1), 99-108.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H314-H313

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. May be harmful in contact with skin.

Sicherheitshinweise: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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