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27318-90-7 - 1,10-Phenanthroline-5,6-dione, 98% - H55747 - Alfa Aesar

H55747 1,10-Phenanthroline-5,6-dione, 98%

CAS-Nummer
27318-90-7
Synonyme

Größe Preis ($) Menge Verfügbarkeit
250mg 49,60
1g 152,00
5g 660,00
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

1,10-Phenanthroline-5,6-dione, 98%

MDL
MFCD00014473

Chemische Eigenschaften

Formel
C12H6N2O2
Molmasse
210.19
Schmelzpunkt
260° dec.
Löslichkeit
Insoluble in water.

Anwendungen

1,10-Phenanthroline-5,6-dione is a Bifunctional quinone oxidant which, when used in conjunction with Zn2+ catalysts, is used to affect the aerobic oxidation of secondary amines to a variety of value added motifs, including indoles.

Bemerkungen

Store in a cool and dark place. Store away from incompatible materials such as oxidizing agents.

Literaturverweise

Charles A. Goss.; Hector D. Abruna. Spectral, electrochemical and electrocatalytic properties of 1,10-phenanthroline-5,6-dione complexes of transition metals. Inorg. Chem. 1985, 24 (25), 4263-4267.

Q. Wu.; M. Maskus.; F. Pariente.; F. Tobalina.; V. M. Fernández.; E. Lorenzo.; H. D. Abruña. Electrocatalytic Oxidation of NADH at Glassy Carbon Electrodes Modified with Transition Metal Complexes Containing 1,10-Phenanthroline-5,6-dione Ligands. Anal. Chem. 1996, 68 (20),3688-3696.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2933.99
TSCA
No

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