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Allylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58012 - Alfa Aesar

H58012 Allylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS-Nummer
Synonyme

Größe Preis ($) Menge Verfügbarkeit
50ml 158,00
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Allylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD22685720

Chemische Eigenschaften

Formel
C3H5BrZn
Molmasse
186.36
Sensitivität
Air Sensitive
Löslichkeit
Reacts with water.

Anwendungen

Allylzinc bromide undergoes addition reaction with nitrile oxide to form 5-butenylisoxazolines.

Bemerkungen

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents and heat.

Literaturverweise

Marcel van der Sluis.; Jan Dalmolen.; Ben de Lange.; Bernard Kaptein.; Richard M. Kellogg.; Quirinus B. Broxterman.Diastereoselective Addition of Allylzinc Bromide to Imines Derived from (R)-Phenylglycine Amide.Org. Lett. 2001, 3 (24),3943-3946.

Marcel van der Sluis.; Jan Dalmolen.; Ben de Lange.; Bernard Kaptein.; Richard M. Kellogg.; Quirinus B. Broxterman. Diastereoselective Addition of Allylzinc Bromide to Imines Derived from (R)-Phenylglycine Amide .Org. Lett. 2001, 3 (24),3943-3946.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H261-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Sicherheitshinweise: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
4.3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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