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7565-59-5 - tert-Butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58351 - Alfa Aesar

H58351 tert-Butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS-Nummer
7565-59-5
Synonyme

Größe Preis ($) Menge Verfügbarkeit
50ml 170,98
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tert-Butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00671989

Chemische Eigenschaften

Formel
C4H9BrZn
Molmasse
202.40
Dichte
0.966
Sensitivität
Air Sensitive
Löslichkeit
Reacts with water.

Anwendungen

It is employed in cross couplig reactions.

Bemerkungen

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents, heat, acids and water.

Literaturverweise

M. V. Hanson.; R. D. Rieke. 1,4-Addition of secondary and tertiary alkylzinc bromides to .alpha.,.beta.-unsaturated ketones without a copper catalyst. J. Am. Chem. Soc. 1995, 117 (43),10775-10776.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H261-H314-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Suspected of causing cancer. May cause respiratory irritation.

Sicherheitshinweise: P210-P231+P232-P260-P201-P261-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
4.3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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