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H58498 3-Pyridylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS-Nummer
Synonyme

Stock No. Größe Preis ($) Menge Verfügbarkeit
H58498-AD 50ml 283,00
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3-Pyridylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD11915899

Chemische Eigenschaften

Formel
C5H4BrNZn
Molmasse
223.38
Storage & Sensitivity
Keep Cold. Air Sensitive. Store under Argon.
Löslichkeit
Reacts with water.

Anwendungen

3-Pyridylzinc bromide used in coupling reaction.

Bemerkungen

Air Sensitive, store away from air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literaturverweise

Seung-Hoi Kim; Reuben D. Rieke. 2-Pyridyl and 3-pyridylzinc bromides: direct preparation and coupling reaction. Tetrahedron. 2010, 66 (17), 3135-3146.

Nadja M. Simkovsky; Monika Ermann; Stanley M. Roberts; David M. Parry; and Andy D. Baxter. Some regioselective cross-coupling reactions of halopyridines and halopyrimidines. J. Chem. Soc., Perkin Trans. 1. 2002, (16), 1847-1849.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H261-H303-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. May be harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Sicherheitshinweise: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
4.3
Verpackungsgruppe
II
Harmonized Tariff Code
2933.39
TSCA
No

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