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38111-44-3 - Phenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58659 - Alfa Aesar

H58659 Phenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS-Nummer
38111-44-3
Synonyme

Größe Preis ($) Menge Verfügbarkeit
50ml 176,13
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Phenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD01319861

Chemische Eigenschaften

Formel
C6H5BrZn
Molmasse
222.39
Dichte
0.99
Sensitivität
Air Sensitive
Löslichkeit
Reacts with water.

Anwendungen

It is used in the cross-coupling reaction.

Bemerkungen

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents, heat, acids and water.

Literaturverweise

Tamio Hayashi.; Akihiro Yamamoto.; Toshiya Hagihara. Stereo- and regiochemistry in palladium-catalyzed nucleophilic substitution of optically active (E)- and (Z)-allyl acetates. J. Org. Chem. 1986, 51 (5),723-727.

Mario Rottländer.; Paul Knochel. Palladium-Catalyzed Cross-Coupling Reactions with Aryl Nonaflates:? A Practical Alternative to Aryl Triflates. J. Org. Chem. 1998, 63 (1),203-208.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H261-H314

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage.

Sicherheitshinweise: P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
4.3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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