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307531-83-5 - 2-(1,3-Dioxolan-2-yl)ethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58916 - Alfa Aesar

H58916 2-(1,3-Dioxolan-2-yl)ethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS-Nummer
307531-83-5
Synonyme

Größe Preis ($) Menge Verfügbarkeit
50ml 217,00
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2-(1,3-Dioxolan-2-yl)ethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD02260129

Chemische Eigenschaften

Formel
C5H9BrO2Zn
Molmasse
246.41
Dichte
0.984
Sensitivität
Air Sensitive
Löslichkeit
Reacts with water.

Anwendungen

It is applied in pharmaceutical industry.

Bemerkungen

Handle under dry protective gas. Keep away from strong oxidizing agents, heat, acid chlorides, bases and acids.

Literaturverweise

Zhe Lu.; Ashraf Wilsily.; Gregory C. Fu. Stereoconvergent Amine-Directed Alkyl-Alkyl Suzuki Reactions of Unactivated Secondary Alkyl Chlorides. J. Am. Chem. Soc. 2011, 133 (21),8154-8157.

Alexander J. Oelke.; Jianwei Sun.; Gregory C. Fu. Nickel-Catalyzed Enantioselective Cross-Couplings of Racemic Secondary Electrophiles That Bear an Oxygen Leaving Group. J. Am. Chem. Soc. 2012, 134 (6),2966-2969.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H261-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Sicherheitshinweise: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
4.3
Verpackungsgruppe
II
Harmonized Tariff Code
2932.99
TSCA
No

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