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16420-13-6 - Dimethylthiocarbamoyl chloride, 95% - H60104 - Alfa Aesar

H60104 Dimethylthiocarbamoyl chloride, 95%

CAS-Nummer
16420-13-6
Synonyme

Größe Preis ($) Menge Verfügbarkeit
25g 57,17
100g 160,57
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Dimethylthiocarbamoyl chloride, 95%

MDL
MFCD00004919

Chemische Eigenschaften

Formel
C3H6ClNS
Molmasse
123.60
Schmelzpunkt
39-43°
Siedepunkt
90-95°
Flammpunkt
98°(208°F)
Sensitivität
Moisture Sensitive
Löslichkeit
Soluble in chloroform and tetrahydrofuran.

Anwendungen

Dimethylthiocarbamoyl chloride is used as an intermediate in the synthesis of pharmaceuticals. It finds application in chemoselective deoxygenation of pyridine-N-oxides. It is also used as a starting reagent in the synthesis of dimethylthiocarbamates.

Bemerkungen

Store in cool place. Moisture sensitive. Incompatible with strong oxidizing agents, amines and strong bases. Reacts violently with water.

Literaturverweise

Zaim, O.; Tuzun, N. S.; Cevik, B.; Ozcan, H.; Boz, E. Synthesis, reactions and DFT study of tropolone N,N-dimethylthiocarbamate. Tetrahedron 2015, 71 (33), 5391-5398.

Gandhi, M. R.; Yamada, M.; Kondo, Y.; Sato, R.; Hamada, F. Synthesis and Characterization of Dimethylthiocarbamoyl-Modified Thiacalix[n]arenes for Selective Pd(II)-Ion Extraction. Ind. Eng. Chem. Res. 2014, 53 (7), 2559-2565.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318-H302-H317

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed. May cause an allergic skin reaction.

Sicherheitshinweise: P260-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
635823
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2930.20
TSCA
Yes

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