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35193-63-6 - 1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99% - H60395 - Alfa Aesar

H60395 1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99%

CAS-Nummer
35193-63-6
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 17,70
5g 71,90
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1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99%

MDL
MFCD00010045
EINECS
252-425-8

Chemische Eigenschaften

Formel
C20H13O4P
Molmasse
348.29
Löslichkeit
Extremely low soluble in water.

Anwendungen

1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, is used as a chiral chemical compound, a chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.

Bemerkungen

Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from strong oxidizing agents.

Literaturverweise

H Nakamura.; A Sano.; H Sumii. Chiral Separation of (R, S)-1, 1'-Binaphthyl-2, 2'-diyl Hydrogenphosphate by Capillary Electrophoresis Using Monosaccharides as Chiral Selectors. Analytical sciences. 199814 (2), 375-378.

GHS Gefahren- und Sicherheitshinweise

Sicherheitshinweise: P260-P201-P280-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2934.99
TSCA
No

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