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80149-80-0 - 4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate, 95% - Carbonic acid 4-nitrophenyl 2-(trimethylsilyl)ethyl ester - Teoc-ONp - H60466 - Alfa Aesar

H60466 4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate, 95%

CAS-Nummer
80149-80-0
Synonyme
Carbonic acid 4-nitrophenyl 2-(trimethylsilyl)ethyl ester
Teoc-ONp

Größe Preis ($) Menge Verfügbarkeit
1g 47,70
5g 193,00
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4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate, 95%

MDL
MFCD00042930
EINECS
279-406-7

Chemische Eigenschaften

Formel
C12H17NO5Si
Molmasse
283.35
Schmelzpunkt
35-40°
Sensitivität
Moisture & Light Sensitive
Löslichkeit
Slightly soluble in water.

Anwendungen

It is employed as a reagent for the introduction of the TEOC-amino protecting group which can be cleaved by F-.

Bemerkungen

Moisture & Light Sensitive. Store at 2-8°C.

Literaturverweise

Andre Rosowsky.; Joel E. Wright. N.µ.-Alkoxycarbonylation of .alpha.,.µ.-diamino acids with 2-(trimethylsilyl)ethyl 4-nitrophenyl carbonate. J. Org. Chem. 1983, 48 (9), 1539-1541.

Takamasa Iimori.; Takafumi Shibazaki.; Shiro Ikegami. A novel intramolecular decarboxylative glycosylation via mixed carbonate. Tetrahedron Lett. 1996, 37 (13),2267-2270.

Weitere Referenzen

Beilstein
4320585
Harmonized Tariff Code
2931.90
TSCA
No

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