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823-96-1 - Trimethylboroxine, 50% w/w soln. in THF - H61464 - Alfa Aesar

H61464 Trimethylboroxine, 50% w/w soln. in THF

CAS-Nummer
823-96-1
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5ml 68,20
25ml 311,00
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Trimethylboroxine, 50% w/w soln. in THF

MDL
MFCD00013354

Chemische Eigenschaften

Formel
C3H9B3O3
Molmasse
125.54
Dichte
0.894
Sensitivität
Moisture Sensitive & Hygroscopic
Löslichkeit
Not miscible in water.

Anwendungen

Trimethylboroxine is used as a derivatizing agent for GLC analysis. It is used in a diverse array of areas, including as a polymerization additive. It is also used in the preparation of CBS catalysts for asymmetric reductions.

Bemerkungen

Moisture and light sensitive. Incompatible with oxidizing agents.

Literaturverweise

Igor Novak; Branka Kovac. On the aromaticity of trimethylboroxine: A photoelectron spectroscopic study. Chemical Physics Letters. 2007, 440,(1-3), 70-72.

 

Takahiro Nishimura; Akram Ashouri; Yusuke Ebe; Yuko Maeda; Tamio Hayashi. Rhodium/chiral diene-catalyzed asymmetric methylation of N-sulfonylarylimines with trimethylboroxine. Tetrahedron: Asymmetry. 2012, 23,(9), 655-658.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H303-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. May be harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Sicherheitshinweise: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1757008
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2934.99
TSCA
Yes

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