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2,2,2-Trifluoroethyl trifluoromethanesulfonate is a powerful trifluoroethylating agent which is useful for synthesis of fluorinated amino acids. It is used as a reagent in thenantioselective preparation of cyclic N-aryl hydroxamic acids via phase-transfer catalyzed alkylation of nitrobenzyl bromides to give nirophenylalanines.
Laura A.McAllister; Bruce M.Bechle; Amy B.Dounay; Edelweiss Evrard; Xinmin Gan; Somraj Ghosh; Ji-Young Kim; Vinod D.Parikh; Jamison B.Tuttle; Patrick R.Verhoest. A general strategy for the synthesis of cyclic N-aryl hydroxamic acids via partial nitro group reduction. Journal of Organic Chemistry. 2011, 76,(9), 3484-3497.
Junji Ichikawa; Hideharu Jyono; Satoshi Yonemaru; Tatsuo Okauchi; Toru Minami. A facile synthesis of 1-H-2,2-difluorovinylphosphorus compounds from 2,2,2-trifluoroethyl trifluoromethanesulfonate and substitutions of their vinylic fluorines. Journal of Fluorine Chemistry. 1999, 97,(1-2), 109-114.
Gefahrenhinweise (EU): H332-H314-H318
Harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.