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60456-23-7 - (S)-(-)-Glycidol, 99+%, ee 99+% - (S)-(-)-Oxirane-2-methanol - (S)-(-)-2,3-Epoxy-1-propanol - H63502 - Alfa Aesar

H63502 (S)-(-)-Glycidol, 99+%, ee 99+%

CAS-Nummer
60456-23-7
Synonyme
(S)-(-)-Oxirane-2-methanol
(S)-(-)-2,3-Epoxy-1-propanol

Größe Preis ($) Menge Verfügbarkeit
1g 23,90
5g 84,70
25g 303,00
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(S)-(-)-Glycidol, 99+%, ee 99+%

MDL
MFCD00074874

Chemische Eigenschaften

Formel
C3H6O2
Molmasse
74.08
Siedepunkt
66-67°/19mm
Flammpunkt
66°(151°F)
Dichte
1.116
Brechungsindex
1.4330
Löslichkeit
Soluble in chloroform, DMSO and methanol.

Anwendungen

(S)-(-)-Glycidol is employed in the synthesis of chiral (E)-allylic alcohol side-chains for introduction into prostacyclin and prostaglandin frameworks by cross-metathesis. Also used as a starting reagent to synthesize non-peptidic HIV protease inhibitors.

Bemerkungen

Store in freezer at(-20°C). Keep container tightly closed. Store away from oxidizing agent.

Literaturverweise

Neil A Sheddan; Johann Mulzer. Cross metathesis as a general strategy for the synthesis of prostacyclin and prostaglandin analogues. Organic Letters. 2006, 8(14), 3101-3104.

Haines TD; Adlaf KJ; Pierceall RM, et al. Direct Determination of MCPD Fatty Acid Esters and Glycidyl Fatty Acid Esters in Vegetable Oils by LC-TOFMS. J. Am. Oil Chem. Soc. 2011, 88(1), 1-14.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H227-H302-H312-H331-H315-H319-H341-H350-H360-H335

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. Suspected of causing genetic defects. May cause cancer. May damage fertility or the unborn child. May cause respiratory irritation.

Sicherheitshinweise: P260-P201-P280a-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves and eye/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
79783
Gefahrenklasse
6.1
Verpackungsgruppe
III
Harmonized Tariff Code
2910.90
TSCA
No
RTECS
RR0508100

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