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60456-23-7 - (S)-(-)-Glycidol, 99+%, ee 99+% - (S)-(-)-Oxirane-2-methanol - (S)-(-)-2,3-Epoxy-1-propanol - H63502 - Alfa Aesar

H63502 (S)-(-)-Glycidol, 99+%, ee 99+%

CAS-Nummer
60456-23-7
Synonyme
(S)-(-)-Oxirane-2-methanol
(S)-(-)-2,3-Epoxy-1-propanol

Größe Preis ($) Menge Verfügbarkeit
1g 22,19
5g 85,49
25g 263,01
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

(S)-(-)-Glycidol, 99+%, ee 99+%

MDL
MFCD00074874

Chemische Eigenschaften

Formel
C3H6O2
Molmasse
74.08
Siedepunkt
66-67°/19mm
Flammpunkt
66°(151°F)
Dichte
1.116
Brechungsindex
1.4330
Löslichkeit
Soluble in chloroform, DMSO and methanol.

Anwendungen

(S)-(-)-Glycidol is employed in the synthesis of chiral (E)-allylic alcohol side-chains for introduction into prostacyclin and prostaglandin frameworks by cross-metathesis. Also used as a starting reagent to synthesize non-peptidic HIV protease inhibitors.

Bemerkungen

Store in freezer at(-20°C). Keep container tightly closed. Store away from oxidizing agent.

Literaturverweise

Neil A Sheddan; Johann Mulzer. Cross metathesis as a general strategy for the synthesis of prostacyclin and prostaglandin analogues. Organic Letters. 2006, 8(14), 3101-3104.

Haines TD; Adlaf KJ; Pierceall RM, et al. Direct Determination of MCPD Fatty Acid Esters and Glycidyl Fatty Acid Esters in Vegetable Oils by LC-TOFMS. J. Am. Oil Chem. Soc. 2011, 88(1), 1-14.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H331-H302-H312-H315-H319-H335-H350-H360-H341-H227

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause cancer. May damage fertility or the unborn child. Suspected of causing genetic defects. Combustible liquid.

Sicherheitshinweise: P210-P201-P261-P280-P281-P305+P351+P338-P304+P340-P311-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
79783
Gefahrenklasse
6.1
Verpackungsgruppe
III
Harmonized Tariff Code
2910.90
TSCA
No
RTECS
RR0508100

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