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100367-39-3 - 4-Bromo-2-methoxypyridine, 98% - H64026 - Alfa Aesar

H64026 4-Bromo-2-methoxypyridine, 98%

CAS-Nummer
100367-39-3
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 37,20
5g 137,00
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4-Bromo-2-methoxypyridine, 98%

MDL
MFCD08277268

Chemische Eigenschaften

Formel
C6H6BrNO
Molmasse
188.02
Schmelzpunkt
25-26°
Siedepunkt
87°/15mm
Löslichkeit
Slightly soluble in water.

Anwendungen

4-Bromo-2-methoxypyridine used in the synhesis of Imidazo [1, 2-a] pyrimidines. Suzuki coupling between 4-methoxyphenylboronic acid and 4-bromo-2-methoxypyridine affords 1, 5-disubstituted pyridones. Starting material used in a synthesis of crown-ester-bipyridines and viologens via sodium or nickel reductive coupling, side chain oxidation and esterification.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, heat.

Literaturverweise

F. Trecourt, M. Mallet, F. Marsais, G. Queguiner.Catalyzed metalation applied to 2-methoxypyridine . J. Org. Chem. 1988, 53 (7), 1367-1371.

Wesley P. Blackaby,; John R. Atack,; Frances Bromidge,; José L. Castro,; Simon C. Goodacre,; David J. Hallett. Imidazo[1,2-a]pyrimidines as functionally selective GABAA ligands. Bioorganic & Medicinal Chemistry Letters. 2005, 16 (5), 1175-1179.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
115199
Harmonized Tariff Code
2933.39
TSCA
No

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