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115314-14-2 - Glycidyl (S)-(+)-3-nitrobenzenesulfonate, 98% - Glycidyl (S)-(+)-nosylate - H64289 - Alfa Aesar

H64289 Glycidyl (S)-(+)-3-nitrobenzenesulfonate, 98%

CAS-Nummer
115314-14-2
Synonyme
Glycidyl (S)-(+)-nosylate

Größe Preis ($) Menge Verfügbarkeit
1g 16,00
5g 50,72
25g 233,81
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Glycidyl (S)-(+)-3-nitrobenzenesulfonate, 98%

MDL
MFCD00064582

Chemische Eigenschaften

Formel
C9H9NO6S
Molmasse
259.23
Schmelzpunkt
63-66°
Sensitivität
Moisture Sensitive
Löslichkeit
Soluble in chloroform, methylene chloride and tetrahydrofuran. Insoluble in hexane.

Anwendungen

Glycidyl (S)-(+)-3-nitrobenzenesulfonate is used in the synthesis of enantiopure bisoprolol by reacting with phenols using cesium fluoride as catalyst. It is also involved in the preparation of orally active HIV-1 protease inhibitor.

Bemerkungen

Moisture sensitive. Store in a cool place. Incompatible with strong oxidizing agents and strong bases.

Literaturverweise

Lee, S.; An, H.; Chang, D. J.; Jang, J.; Kim, K.; Sim, J.; Lee, J.; Suh, Y. G. Total synthesis of (-)-deguelin via an iterative pyran-ring formation strategy. Chem. Commun. 2015, 51 (43), 9026-9029.

Iwahashi, M.; Shimabukuro, A.; Onoda, T.; Matsunaga, Y.; Okada, Y.; Matsumoto, R.; Nambu, F.; Nakai, H.; Toda, M. Discovery of selective indole-based prostaglandin D2 receptor antagonist. Bioorg. Med. Chem. 2011, 19 (15), 4574-4588.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
4704457
Harmonized Tariff Code
2910.90
TSCA
No
RTECS
DB7192010

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