H64289 Glycidyl (S)-(+)-3-nitrobenzenesulfonate, 98%
SDS
| Stock No. | Größe | Preis ($) | Menge | Verfügbarkeit |
|---|---|---|---|---|
| H64289-03 | 1g | 20,40 |
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| H64289-06 | 5g | 64,70 |
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| H64289-14 | 25g | 232,00 |
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Glycidyl (S)-(+)-3-nitrobenzenesulfonate, 98%
Chemische Eigenschaften
Anwendungen
Glycidyl (S)-(+)-3-nitrobenzenesulfonate is used in the synthesis of enantiopure bisoprolol by reacting with phenols using cesium fluoride as catalyst. It is also involved in the preparation of orally active HIV-1 protease inhibitor.
Bemerkungen
Literaturverweise
Lee, S.; An, H.; Chang, D. J.; Jang, J.; Kim, K.; Sim, J.; Lee, J.; Suh, Y. G. Total synthesis of (-)-deguelin via an iterative pyran-ring formation strategy. Chem. Commun. 2015, 51 (43), 9026-9029.
Iwahashi, M.; Shimabukuro, A.; Onoda, T.; Matsunaga, Y.; Okada, Y.; Matsumoto, R.; Nambu, F.; Nakai, H.; Toda, M. Discovery of selective indole-based prostaglandin D2 receptor antagonist. Bioorg. Med. Chem. 2011, 19 (15), 4574-4588.
GHS Gefahren- und Sicherheitshinweise
Gefahrenhinweise (EU): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
