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3886-70-2 - (R)-(+)-1-(1-Naphthyl)ethylamine, 97% - H66696 - Alfa Aesar

H66696 (R)-(+)-1-(1-Naphthyl)ethylamine, 97%

CAS-Nummer
3886-70-2
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 17,50
25g 76,90
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(R)-(+)-1-(1-Naphthyl)ethylamine, 97%

MDL
MFCD00064114
EINECS
223-425-5

Chemische Eigenschaften

Formel
C12H13N
Molmasse
171.24
Siedepunkt
152-153°/11mm
Flammpunkt
>110°(230°F)
Dichte
1.060
Brechungsindex
1.6230
Sensitivität
Air Sensitive
Löslichkeit
Soluble in water (<10/l).

Anwendungen

It is used in chiral synthesis in organic reactions including the synthesis of β-amino acids and the enantioselective of ketones to nitroolefins. Also used as absolute configuration of primary amines determined using chiral (2-nitrophenyl)proline amides and H NMR.

Bemerkungen

Air Sensitive, store away from air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literaturverweise

Hee Choon Ahn; Kihang Choi. N-(2-Nitrophenyl)proline: an intramolecular hydrogen bond forming reagent for the determination of the absolute configuration of primary amines.Organic Letters.,2007, 9(19), 3853-3855.

Svetlana B. Tsogoeva; and Shengwei Wei. Highly enantioselective addition of ketones to nitroolefins catalyzed by new thiourea-amine bifunctional organocatalysts. Chem. Commun., 2006, (13),1451-1453.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H312-H314-H318

Toxic if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P280-P301+P310-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
2208025
Gefahrenklasse
8
Verpackungsgruppe
III
Harmonized Tariff Code
2921.49
TSCA
Yes

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