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Thiamine pyrophosphate is used in studies to assess decarboxylation mechanisms in biological systems. It is an important raw material and intermediate used in organic synthesis.
K Aoki.; H Yamazaki. A model for coenzyme-metal ion-apoenzyme interactions: crystal structure of the ternary complex [(thiamine pyrophosphate)(1,10-phenanthroline)aquacopper]-dinitrate-water. J. Am. Chem. Soc. 1980, 102, (22), 6878-6880.
LJ Reynolds.; GA Garcia.; JW Kozarich.; GL Kenyon. Differential reactivity in the processing of [p-(halomethyl) benzoyl] formates by benzoylformate decarboxylase, a thiamine pyrophosphate dependent enzyme. Biochemistry. 1988, 27, (15), 5530-5538.