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484-11-7 - 2,9-Dimethyl-1,10-phenanthroline, 98% - Neocuproine - J63698 - Alfa Aesar

J63698 2,9-Dimethyl-1,10-phenanthroline, 98%

CAS-Nummer
484-11-7
Synonyme
Neocuproine

Größe Preis ($) Menge Verfügbarkeit
5g 41,20
25g 192,61
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2,9-Dimethyl-1,10-phenanthroline, 98%

MDL
MFCD00004973
EINECS
207-601-9

Chemische Eigenschaften

Formel
C14H12N2
Molmasse
208.26
Form
Powder
Schmelzpunkt
159-164°
Sensitivität
Light Sensitive
Löslichkeit
Slightly soluble in water and light petroleum. Soluble in methanol, ethanol, acetone, ether and benzene.

Anwendungen

2,9-Dimethyl-1,10-phenanthroline is used as a reagent for the colorimetric determination of copper and acts as a chelating agent. It is also used in the synthesis of arly ketones.

Bemerkungen

Incompatible with strong oxidizing agents.

Literaturverweise

Ashbrook, L. N.; Elliott, C. M. Dye-Sensitized Solar Cell Studies of a Donor-Appended Bis(2,9-dimethyl-1,10-phenanthroline) Cu(I) Dye Paired with a Cobalt-Based Mediator. J. Phys. Chem. C 2013, 117 (8), 3853-3864.

Xiao, C-L.; Wang, C-Z.; Yuan, L-Y.; Li, B.; He, H.; Wang, S.; Zhao, Y-L.; Chai, Z-F.; Shi, W-Q. Excellent Selectivity for Actinides with a Tetradentate 2,9-Diamide-1,10-Phenanthroline Ligand in Highly Acidic Solution: A Hard-Soft Donor Combined Strategy. Inorg. Chem. 2014, 53 (3), 1712-1720.

Ashbrook, L. N.; Elliott, C. M. Dye-Sensitized Solar Cell Studies of a Donor-Appended Bis(2,9-dimethyl-1,10-phenanthroline) Cu(I) Dye Paired with a Cobalt-Based Mediator. J. Phys. Chem. C. 2013, 117 (8), 3853-3864.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,6449
Harmonized Tariff Code
2933.99
TSCA
Yes
RTECS
SF8380000

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