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15186-48-8 - 2,3-O-Isopropylidene-D-glyceraldehyde, 50% w/w in dichloromethane - 2,2-(R)-Dimethyl-1,3-dioxolane-4-carboxaldehyde - J66337 - Alfa Aesar

J66337 2,3-O-Isopropylidene-D-glyceraldehyde, 50% w/w in dichloromethane

CAS-Nummer
15186-48-8
Synonyme
2,2-(R)-Dimethyl-1,3-dioxolane-4-carboxaldehyde

Größe Preis ($) Menge Verfügbarkeit
1g 53,55
5g 105,06
10g 200,85
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

2,3-O-Isopropylidene-D-glyceraldehyde, 50% w/w in dichloromethane

MDL
MFCD00269682

Chemische Eigenschaften

Formel
C6H10O3
Molmasse
130.14
Form
Liquid
Flammpunkt
62°(144°F)
Brechungsindex
1.454
Löslichkeit
Difficult to mix.

Anwendungen

Reactant involved in organic reactions including, Henry condensation reactions, Synthesis of highly functionalized chiral aziridines, Olefination of aldehydes, C-H oxidations, Aldol-type condensations, Synthesis of hydrophilic pyrazine dyes for use as exogenous fluorescent tracer agents.

Bemerkungen

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literaturverweise

Steinar Hagen.; Thorleif Anthonsen.; Lars Kilaas. Addition of diazomethane and sulfur ylides to the oxo-group in derivatives of ketoses and aldoses : I. Reactions of 2,3-O-isopropylidene-D-glyceraldehyde. Tetrahedron. 1979, 35, (21), 2583-2589.

Brigitte Hafele.; Volker Jager. A Short Synthesis of (S)-5-Hydroxy-2-penten-4-olide from D-Mannitol via 2,3-O-Isopropylidene-D-glyceraldehyde. Liebigs Annalen der Chemie. 1987, 1987, (1), 85-87.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H351-H227

Suspected of causing cancer. Combustible liquid.

Sicherheitshinweise: P210-P201-P280-P281-P202-P308+P313-P370+P378a-P405-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Do not handle until all safety precautions have been read and understood. IF exposed or concerned: Get medical advice/attention. In case of fire: Use for extinction: CO2, powder or water spray. Store locked up. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
6.1
Verpackungsgruppe
III
Harmonized Tariff Code
2932.99
TSCA
No

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