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25581-41-3 - 2,3-O-Isopropylidene-D-erythronolactone, 98% - J66871 - Alfa Aesar

J66871 2,3-O-Isopropylidene-D-erythronolactone, 98%

CAS-Nummer
25581-41-3
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 63,60
5g 222,00
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2,3-O-Isopropylidene-D-erythronolactone, 98%

MDL
MFCD00134440

Chemische Eigenschaften

Formel
C7H10O4
Molmasse
158.15
Form
Powder
Schmelzpunkt
67-69°
Löslichkeit
Soluble in water

Anwendungen

It undergoes Aldol condensations with silyl ketene acetals.1 Employed in spiroannulated carbohydrate synthesis.2 Convergent syntheses of a hydroxylated indolizidine,3 carbohydrate substituted benzoquinones,4 and of the oxazole segment of calyculin5 have been accomplished using this chiral synthon.

Bemerkungen

Store at room temperature. Incompatible with heat, oxidizing agents.

Literaturverweise

Jason L. McCartney.; Christopher T. Meta.; Robert M. Cicchillo.; Matthew D. Bernardina.; Timothy R. Wagner.; Peter Norris. Addition of Lithiated C-Nucleophiles to 2,3-O-Isopropylidene-d-erythronolactone:? Stereoselective Formation of a Furanose C-Disaccharide.J. Org. Chem. 2003, 68 (26),10152-10155 .

GHS Gefahren- und Sicherheitshinweise

Sicherheitshinweise: P260u-P201-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1282952
Harmonized Tariff Code
2932.99
TSCA
No

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Chemikalien

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Metalle und Stoffe

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