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2007-97-8 - 1,2-Phenylene phosphorotrichloridite, 94% - Catechyl phosphorus trichloride - 2,2,2-Trichloro-1,3,2-benzodioxaphosphole - L00227 - Alfa Aesar

L00227 1,2-Phenylene phosphorotrichloridite, 94%

CAS-Nummer
2007-97-8
Synonyme
Catechyl phosphorus trichloride
2,2,2-Trichloro-1,3,2-benzodioxaphosphole

Größe Preis ($) Menge Verfügbarkeit
25g 118,00
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1,2-Phenylene phosphorotrichloridite, 94%

MDL
MFCD00014578
EINECS
217-913-7

Chemische Eigenschaften

Formel
C6H4Cl3O2P
Molmasse
245.43
Schmelzpunkt
48-50°
Siedepunkt
102-104°/2mm
Sensitivität
Moisture Sensitive

Literaturverweise

Reagent for conversion of carboxylic acids and esters to acyl chlorides, carbonyl compounds to gem-dichlorides and amides to nitriles: Chem. Ber., 96, 1387 (1963).

/n

Superior to P2O5 for conversion of medium-ring ketones to 1-chlorocycloalkenes: Chem. Ber., 99, 1414 (1966).

/n

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
743959
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
No

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