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tert-Butyl carbamate is used in palladium-catalyzed synthesis of N-Boc-protected anilines. It was used in the synthesis of tetrasubstituted pyrroles, functionalized with ester or ketone groups at C-3 position.
Peter. Politzer, Jack W. Timberlake. Anomalous properties of halogen substituents. J. Org. Chem. 1972, 37, (22), 3557-3559.
Reacts with allylic selenides in the presence of NCS and base to give carbamates of allylic amines, via [2,3]-sigmatropic rearrangement of an intermediate selenimide: J. Org. Chem., 49, 3647 (1984):
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