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5187-82-6 - (Ethoxycarbonylmethyl)dimethylsulfonium bromide, 98% - (Carboethoxymethyl)dimethylsulfonium bromide - L00266 - Alfa Aesar

L00266 (Ethoxycarbonylmethyl)dimethylsulfonium bromide, 98%

CAS-Nummer
5187-82-6
Synonyme
(Carboethoxymethyl)dimethylsulfonium bromide

Größe Preis ($) Menge Verfügbarkeit
10g 47,50
50g 147,00
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(Ethoxycarbonylmethyl)dimethylsulfonium bromide, 98%

MDL
MFCD00830557
EINECS
225-968-3

Chemische Eigenschaften

Formel
C6H13BrO2S
Molmasse
229.14
Schmelzpunkt
ca 80° dec.

Literaturverweise

The derived ylide does not add to carbonyl compounds, although it does undergo 1,4-addition to enones, with formation of cyclopropanecarboxylic esters: Tetrahedron, 23, 545, (1967); J. Org. Chem., 34, 1240 (1969).

/n

Review of the chemistry of sulfonium ylides: Russ. Chem. Rev., 50, 481 (1981).

/n

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
4161472
Harmonized Tariff Code
2930.90
TSCA
No
RTECS
WR7600000

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