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16466-61-8 - Di-tert-butyl hydrazodicarboxylate, 98+% - N,N'-Di-tert-butoxycarbonylhydrazine - Di-tert-butyl hydrazodiformate - L00280 - Alfa Aesar

L00280 Di-tert-butyl hydrazodicarboxylate, 98+%

CAS-Nummer
16466-61-8
Synonyme
N,N'-Di-tert-butoxycarbonylhydrazine
Di-tert-butyl hydrazodiformate

Größe Preis ($) Menge Verfügbarkeit
5g 50,40
25g 195,00
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Di-tert-butyl hydrazodicarboxylate, 98+%

MDL
MFCD00015000
EINECS
240-512-3

Chemische Eigenschaften

Formel
C10H20N2O4
Molmasse
232.28
Schmelzpunkt
123-126°
Löslichkeit
Insoluble in water.

Anwendungen

Di-tert-butyl hydrazodicarboxylate, is used as starting reagent during the four-step synthesis of the aminobicyclopyrazolone hydrochloride. It was used as reagent during Pd-catalyzed amination reactions of halo-pyridine substrates.

Bemerkungen

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literaturverweise

Paul Dowd.; Hermann Irngartinger. Tricyclo[2.1.0.02,5]pentane and its derivatives. Chem. Rev. 1989, 89, (5), 985-996.

Paul. Dowd.; Wonghil. Chang.; Yi Hyon. Paik. Tetramethyleneethane, a ground-state triplet. J. Am. Chem. Soc. 1986, 108, (23), 7416-7417.

Effective catalyst, in combination with CuCl : phenanthroline, for the aerobic oxidation of a variety of alcohols, aliphatic primary or secondary, benzylic or allylic to aldehydes or ketones. The method has potential as an ecologically benign process, since water is the only by-product: J. Org. Chem., 64, 2433 (1999):

Weitere Referenzen

Beilstein
1794023
Harmonized Tariff Code
2927.00
TSCA
No

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