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1865-01-6 - 4-Nitrophenyl formate, 98% - Formic acid 4-nitrophenyl ester - L00316 - Alfa Aesar

L00316 4-Nitrophenyl formate, 98%

CAS-Nummer
1865-01-6
Synonyme
Formic acid 4-nitrophenyl ester

Größe Preis ($) Menge Verfügbarkeit
5g 43,90
25g 161,00
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4-Nitrophenyl formate, 98%

MDL
MFCD00014713
EINECS
217-473-6

Chemische Eigenschaften

Formel
C7H5NO4
Molmasse
167.12
Schmelzpunkt
70-74°
Sensitivität
Moisture & Light Sensitive
Löslichkeit
Hydrolyzes in water. Soluble in dichloromethane.

Anwendungen

Convenient and selective reagent for the selective formylation of terminal amino groups in such basic amino acids as ornithine or lysine and formylation of α-amino groups in peptides.

Bemerkungen

Moisture and light sensitive. Store away from water/moisture, oxidizing agents and light. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store in dark. Store under inert gas. Protect from exposure to light.

Literaturverweise

Dimitrios Stefanidis, et al. Structure-reactivity correlations for reactions of substituted phenolate anions with acetate and formate esters.J. Am. Chem. Soc.,1993,115,(5), 1650-1656.

Satyendra Kumar, et al. Production, purification, and characterization of lipase from thermophilic and alkaliphilic Bacillus coagulans BTS-3.Protein Expression and Purification.,2005,41,(1), 38-44.

Convenient and selective reagent for the formylation of amino groups: Bull. Chem. Soc. Jpn., 36, 754 (1963); Synthesis, 979 (1982); Synth. Commun., 29, 1819 (1999).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1950897
Harmonized Tariff Code
2915.90
TSCA
Yes

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