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28460-01-7 - Diethyl methylthiomethylphosphonate, 97% - Methylthiomethylphosphonic acid diethyl ester - L00579 - Alfa Aesar

L00579 Diethyl methylthiomethylphosphonate, 97%

CAS-Nummer
28460-01-7
Synonyme
Methylthiomethylphosphonic acid diethyl ester

Größe Preis ($) Menge Verfügbarkeit
5g 55,31
25g 195,20
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Diethyl methylthiomethylphosphonate, 97%

MDL
MFCD00015131

Chemische Eigenschaften

Formel
C6H15O3PS
Molmasse
198.22
Siedepunkt
70-72°/0.2mm
Flammpunkt
101°(213°F)
Dichte
1.130
Brechungsindex
1.4660
Löslichkeit
It is insoluble in water.

Anwendungen

Diethyl methylthiomethylphosphonate, is used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. Diethyl(methylthiomethyl) phosphonate is a reactant for the synthesis of (+)-minfiensine via organocatalytic Diels-Alder/amine cyclization and 6-exo-dig radical cyclization. It is used in the preparation of fused nitrogen, sulfur, and phosphorus containing heterocyclic and relevant difurylpyridazine phosphonates with antimicrobial activity. It is also used as a reactant used in the preparation of fused heterocyclic.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.

Literaturverweise

EJ Corey.; JI Shulman. Application of lithium reagents from (1-methylthio) alkylphosphonate esters to the synthesis of ketones. The Journal of Organic Chemistry. 197035,(3) , 777-780.

J Motoyoshiya.; Y Hongo.; H Tanaka. A Convenient Synthesis of 1, 4-Diketones. Synthetic Communications. . 199121,(8-9) , 997-1000.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319

Causes skin irritation. Causes serious eye irritation.

Sicherheitshinweise: P280-P264-P305+P351+P338-P362-P321-P332+P313-P337+P313-P302+P352

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: IF ON SKIN: Wash with plenty of soap and water.

Weitere Referenzen

Beilstein
1705833
Harmonized Tariff Code
2931.90
TSCA
No

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