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1016-58-6 - 4,5-Dimethoxy-2-nitrobenzyl alcohol, 98% - 6-Nitroveratryl alcohol - L00719 - Alfa Aesar

L00719 4,5-Dimethoxy-2-nitrobenzyl alcohol, 98%

CAS-Nummer
1016-58-6
Synonyme
6-Nitroveratryl alcohol

Größe Preis ($) Menge Verfügbarkeit
5g 69,70
25g 271,00
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4,5-Dimethoxy-2-nitrobenzyl alcohol, 98%

MDL
MFCD00014701
EINECS
213-806-4

Chemische Eigenschaften

Formel
C9H11NO5
Molmasse
213.19
Schmelzpunkt
144-148°
Sensitivität
Light Sensitive
Löslichkeit
Soluble in water.

Anwendungen

4,5-Dimethoxy-2-nitrobenzyl alcohol, is used as Reagent for the protection of alcohols, etc., as ethers which can be cleaved by photolysis involving intramolecular rearrangement to derivatives of o-nitrosobenzaldehyde, which are readily cleaved by hydrolysis. It is also used as photochemical protecting groups in organic synthesis. It is also used as a pharmaceutical intermediate.

Bemerkungen

Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.

Literaturverweise

S Kantevari.; CV Narasimhaji.; HB Mereyala. Bis (4, 5-dimethoxy-2-nitrophenyl) ethylene glycol: a new and efficient photolabile protecting group for aldehydes and ketones. Tetrahedron. 200561,(24) , 5849-5854.

H Zhao.; ES Sterner.; EB Coughlin.; P Theato. o-Nitrobenzyl alcohol derivatives: opportunities in polymer and materials science. Macromolecules. 201245,(4) , 1723-1736.

Reagent for the protection of alcohols, etc., as ethers which can be cleaved by photolysis involving intramolecular rearrangement to derivatives of o-nitrosobenzaldehyde, which are readily cleaved by hydrolysis: J. Am. Chem. Soc., 92, 6333 (1970); J. Org. Chem., 37, 2281, 2285 (1972).

For reviews of photochemical protecting groups in organic synthesis, see: Synthesis, 1 (1980); Org. Photochem., 9, 225 (1987).

Weitere Referenzen

Beilstein
1880093
Harmonized Tariff Code
2909.30
TSCA
No

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