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627-27-0 - 3-Buten-1-ol, 98+% - Allyl carbinol - L00767 - Alfa Aesar

L00767 3-Buten-1-ol, 98+%

CAS-Nummer
627-27-0
Synonyme
Allyl carbinol

Größe Preis ($) Menge Verfügbarkeit
5g 31,52
25g 111,24
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3-Buten-1-ol, 98+%

MDL
MFCD00002959
EINECS
210-991-3

Chemische Eigenschaften

Formel
CH2=CHCH2CH2OH
Molmasse
72.11
Siedepunkt
113-114°
Flammpunkt
32°(89°F)
Dichte
0.841
Brechungsindex
1.4210
Löslichkeit
Soluble in water.

Anwendungen

3-Buten-1-ol is employed in a study of the Mn-catalyzed hydrohydrazination of olefins. Also used in a study of the conversion of propargylic acetates to ethers catalyzed by ferric chloride.

Bemerkungen

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literaturverweise

Francisco Caturla.; Carmen Najera. Preparation and synthetic applications of lithiated vinyl sulfones derived from 3-buten-1-ol and 4-penten-1-ol. Tetrahedron. 1997, 53, (33), 11449-11464.

Naoki Yamamoto.; Satoshi Sato.; Ryoji Takahashi.; Kanichiro Inui. Synthesis of 3-buten-1-ol from 1,4-butanediol over ZrO2 catalyst. Journal of Molecular Catalysis A: Chemical. 2006, 243, (1), 52-59.

Can be used to protect enolizable and base-sensitive carboxylic acids as their 3-butenyl esters which can be cleaved by ozonolysis, followed by treatment with DBU or triethylamine: Tetrahedron Lett., 30, 7317 (1989).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1633504
Gefahrenklasse
3
Verpackungsgruppe
III
Harmonized Tariff Code
2905.29
TSCA
Yes

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