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3-Buten-1-ol is employed in a study of the Mn-catalyzed hydrohydrazination of olefins. Also used in a study of the conversion of propargylic acetates to ethers catalyzed by ferric chloride.
Francisco Caturla.; Carmen Najera. Preparation and synthetic applications of lithiated vinyl sulfones derived from 3-buten-1-ol and 4-penten-1-ol. Tetrahedron. 1997, 53, (33), 11449-11464.
Naoki Yamamoto.; Satoshi Sato.; Ryoji Takahashi.; Kanichiro Inui. Synthesis of 3-buten-1-ol from 1,4-butanediol over ZrO2 catalyst. Journal of Molecular Catalysis A: Chemical. 2006, 243, (1), 52-59.
Can be used to protect enolizable and base-sensitive carboxylic acids as their 3-butenyl esters which can be cleaved by ozonolysis, followed by treatment with DBU or triethylamine: Tetrahedron Lett., 30, 7317 (1989).
Gefahrenhinweise (EU): H226-H315-H319-H335
Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.