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Selective oxidant which converts benzylic alcohols to aldehydes in high yield: J. Chem. Soc., Chem. Commun., 952 (1978); Tetrahedron Lett., 3331 (1979); J. Org. Chem., 46, 1442 (1981). Oxidizes phenols to o-quinones: J. Chem. Soc., Perkin 1, 1473 (1981): Tetrahedron, 44, 6397 (1988):/n
Reagent for the dehydrogenation of ketones to ɑß-enones and of cyclic enones to dienones: J. Chem. Soc., Perkin 1, 2209 (1980); J. Chem. Soc., Chem. Commun., 1044 (1981). δ-Lactones are also converted to their ɑß-unsaturated derivatives: J. Chem. Soc., Perkin 1, 1919 (1982). Hydrazines can be converted to azo compounds; hydrazine itself gives diimide: J. Org. Chem., 46, 1564 (1981). 3-Substituted indolines give indoles: J. Chem. Soc., Perkin 1, 707 (1990)./n
Monograph: Organoselenium Chemistry, D. Liotta, Ed., Wiley, N.Y. (1987)./n
Gefahrenhinweise (EU): H301-H331-H373
Toxic if swallowed. Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure.
Avoid release to the environment. Do not eat, drink or smoke when using this product. IF exposed or if you feel unwell: Immediately call a POISON CENTER/doctor IF ON SKIN: Wash with plenty of water. Dispose of contents/container in accordance with local/regional/national/international regulations.