Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

433-27-2 - Trifluoroacetaldehyde ethyl hemiacetal, tech. 80% - L01554 - Alfa Aesar

L01554 Trifluoroacetaldehyde ethyl hemiacetal, tech. 80%

CAS-Nummer
433-27-2
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 49,70
25g 183,00
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Trifluoroacetaldehyde ethyl hemiacetal, tech. 80%

MDL
MFCD00000441
EINECS
207-087-6

Chemische Eigenschaften

Formel
C4H7F3O2
Molmasse
144.09
Siedepunkt
104-106°
Flammpunkt
39°(102°F)
Dichte
1.230
Brechungsindex
1.3430

Literaturverweise

Reacts with nucleophilic organosilanes, e.g. allyltrimethylsilane, TMS cyanide or silyl enol ethers, in the presence of a Lewis acid (ZnI2 or AlCl3) to give a series of ɑ-trifluoromethylated alcohols in high yield: Tetrahedron Lett., 33, 1351 (1992).

/n

The synthesis of ɑ-trifluoromethylated alcohols has also been accomplished by In-mediated reaction with allylic bromides in water: Chem. Commun., 1929 (1996).

/n

For a review applications in the synthesis of trifluoromethylated compounds, see: Current Org. Chem., 8, 1659 (2004).

/n

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H226-H302-H315-H319

Flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation.

Sicherheitshinweise: P210-P280-P240-P241-P303+P361+P353-P305+P351+P338-P362-P301+P312-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
906797
Gefahrenklasse
3
Verpackungsgruppe
III
Harmonized Tariff Code
2911.00
TSCA
Yes
RTECS
KK9000000

Empfohlen

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf