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3481-02-5 - Cyclopropyl phenyl ketone, 97% - Benzoylcyclopropane - L02218 - Alfa Aesar

L02218 Cyclopropyl phenyl ketone, 97%

CAS-Nummer
3481-02-5
Synonyme
Benzoylcyclopropane

Größe Preis ($) Menge Verfügbarkeit
25g 62,00
100g 193,00
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Cyclopropyl phenyl ketone, 97%

MDL
MFCD00001294
EINECS
222-458-2

Chemische Eigenschaften

Formel
C10H10O
Molmasse
146.19
Siedepunkt
248°
Flammpunkt
90°(194°F)
Dichte
1.06
Brechungsindex
1.5534
Löslichkeit
Insoluble in water.

Anwendungen

Cyclopropyl phenyl ketone is used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It is also used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.

Bemerkungen

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literaturverweise

W. J. Close. An Improved Synthesis of Cyclopropyl Phenyl Ketone and Related Substances. J. Am. Chem. Soc. 1957, 79 (6), 1455-1458.

Frank J. Piehl.; Weldon G. Brown. Alkylation of Cyclopropyl Phenyl Ketone. J. Am. Chem. Soc. 1953, 75(20), 5023-5026.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H227

Combustible liquid.

Sicherheitshinweise: P210u-P280a-P370+P378a-P403+P235-P501a

Wear protective gloves and eye/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1860145
Harmonized Tariff Code
2914.39
TSCA
No

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