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874-23-7 - 2-Acetylcyclohexanone, 98% - L02753 - Alfa Aesar

L02753 2-Acetylcyclohexanone, 98%

CAS-Nummer
874-23-7
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 29,50
25g 71,70
100g 211,00
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

2-Acetylcyclohexanone, 98%

MDL
MFCD00001633
EINECS
212-858-5

Chemische Eigenschaften

Formel
C8H12O2
Molmasse
140.18
Siedepunkt
111-112°/18mm
Flammpunkt
79°(174°F)
Dichte
1.063
Brechungsindex
1.5110
Löslichkeit
Not miscible in water.

Anwendungen

2-Acetylcyclohexanone is useful for synthesis of anilinoethanolamines, 1-(pyridyl)ethanol derivatives that can reduce keto-esters and ketones. It is also used in the synthesis of phenothiazine derivatives that can inhibit prote in farnesyltransferase molecules and some that show anti-proliferative activity.

Bemerkungen

Incompatible with Strong oxidizing agents, Strong bases. Air-sensitive.

Literaturverweise

Emilia Iglesias. Tautomerization of 2-Acetylcyclohexanone. 1. Characterization of Keto-Enol/Enolate Equilibria and Reaction Rates in Water.J. Org. Chem.2003, 68 (7), 2680-2688.

Fillmore Freeman; Donald K. Fraquhar; Robert L. Walker. Reaction of 2-acetylcyclohexanone with malononitrile and cyanoacetamide.J. Org. Chem.1968, 33 (9), 3648-3650.

For conversion to the ɑß-unsaturated diketone by selenoxide elimination, see Phenyl­selenenyl­ chloride, A12751.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H227

Combustible liquid.

Sicherheitshinweise: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1858621
Harmonized Tariff Code
2914.29
TSCA
Yes

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