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768-32-1 - Phenyltrimethylsilane, 99% - Trimethylphenylsilane - L02876 - Alfa Aesar

L02876 Phenyltrimethylsilane, 99%

CAS-Nummer
768-32-1
Synonyme
Trimethylphenylsilane

Größe Preis ($) Menge Verfügbarkeit
5g 22,70
25g 73,90
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Phenyltrimethylsilane, 99%

MDL
MFCD00008271
EINECS
212-192-5

Chemische Eigenschaften

Formel
C9H14Si
Molmasse
150.30
Siedepunkt
169-170°
Flammpunkt
40°(104°F)
Dichte
0.871
Brechungsindex
1.4900
Löslichkeit
Not miscible or difficult to mix with water.

Anwendungen

It is employed as intermediate for pharmaceutical and organic synthesis.

Bemerkungen

Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literaturverweise

Ralph J. Fessenden; Ray A. Hartman. Metabolic fate of phenyltrimethylsilane and phenyldimethylsilane. J. Med. Chem., 1970,13(1), 52-54.

J. A. Bedford; J. R. Bolton; A. Carrington; and R. H. Prince. The electron spin resonance spectra of the phenyltrimethylsilane and -germane anions: π-bonding between silicon and germanium and the aromatic ring. Trans. Faraday Soc.., 1963,5953-58.

Reagent, in combination with iodine, for cleavage of esters and ethers, cf Iodotrimethyl­silane, A12902. Reported to be superior to TMS iodide for the cleavage of aryl ethers: Synthesis, 417 (1977).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H226-H315-H319

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation.

Sicherheitshinweise: P261-P280g-P305+P351+P338

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Weitere Referenzen

Beilstein
1855012
Gefahrenklasse
3
Verpackungsgruppe
III
Harmonized Tariff Code
2931.90
TSCA
Yes

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