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79-15-2 - N-Bromoacetamide, 95% - L02953 - Alfa Aesar

L02953 N-Bromoacetamide, 95%

CAS-Nummer
79-15-2
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 61,52
25g 237,60
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N-Bromoacetamide, 95%

MDL
MFCD00037097
EINECS
201-181-0

Chemische Eigenschaften

Formel
C2H4BrNO
Molmasse
137.97
Schmelzpunkt
102-106°
Löslichkeit
Soluble in water.

Anwendungen

Abolishes the rapid inactivation of membrane sodium- and potassium-ion channels.

Bemerkungen

Store at -20°C. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literaturverweise

D R Matteson; and P Carmeliet. Modification of K channel inactivation by papain and N-bromoacetamide. Biophysical Journal., 1988,53(4), 641-645.

J Tanguy and J Z Yeh. BTX modification of Na channels in squid axons. I. State dependence of BTX action. Journal of General Physiology., 1991,97(3), 499-519.

Source of positive bromine, useful for the conversion of alkenes to bromohydrins under mild conditions: Helv. Chim. Acta, 26, 562, 746, 1799 (1943); Tetrahedron Lett., 765 (1973). It is also a useful reagent for mild oxidation of secondary alcohols to ketones: J. Biol. Chem., 184, 393 (1950); J. Am. Chem. Soc., 76, 3682 (1954); 85, 1409 (1963).

In combination with AgOAc and AcOH, has been used to convert alkenes stereoselectively to cis-1,2-diols: Tetrahedron Lett., 1581 (1976).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H319-H335

Causes severe skin burns and eye damage. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P280-P303+P361+P353-P305+P351+P338-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Weitere Referenzen

Merck
14,1398
Beilstein
969346
Harmonized Tariff Code
2924.19
TSCA
Yes

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