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437-17-2 - Triphenylcarbenium hexafluorophosphate, 98% - Tritylium hexafluorophosphate - Trityl hexafluorophosphate - L03140 - Alfa Aesar

L03140 Triphenylcarbenium hexafluorophosphate, 98%

CAS-Nummer
437-17-2
Synonyme
Tritylium hexafluorophosphate
Trityl hexafluorophosphate

Größe Preis ($) Menge Verfügbarkeit
10g 60,30
50g 258,00
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Triphenylcarbenium hexafluorophosphate, 98%

MDL
MFCD00013121
EINECS
207-112-0

Chemische Eigenschaften

Formel
C19H15F6P
Molmasse
388.29
Schmelzpunkt
ca 160° dec.
Sensitivität
Moisture Sensitive
Löslichkeit
Soluble in water. (27 g/L) at 25°C.

Anwendungen

Triphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of "push-pull" tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.

Bemerkungen

Moisture Sensitive. Store at 4°C. Store away from oxidizing agents and strong bases. Incompatible with heat and water.

Literaturverweise

Jan Voigt; Thomas Braun. Si-H and Si-Si activation at Pt: synthesis and reactivity of neutral and cationic silyl complexes.Dalton Transactions.2011, 40 (47), 12699-12704.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P310a

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

Weitere Referenzen

Beilstein
4344297
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2942.00
TSCA
Yes

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