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924-41-4 - 1,5-Hexadien-3-ol, 95% - Allyl vinyl carbinol - L03182 - Alfa Aesar

L03182 1,5-Hexadien-3-ol, 95%

CAS-Nummer
924-41-4
Synonyme
Allyl vinyl carbinol

Größe Preis ($) Menge Verfügbarkeit
2g 29,97
10g 82,62
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1,5-Hexadien-3-ol, 95%

MDL
MFCD00008662
EINECS
213-102-7

Chemische Eigenschaften

Formel
C6H10O
Molmasse
98.15
Siedepunkt
133-134°
Flammpunkt
29°(84°F)
Dichte
0.877
Brechungsindex
1.4480
Löslichkeit
Sparingly Soluble.

Anwendungen

1,5-Hexadien-3-ol is used in the synthesis of (+)-obtusenyne. It is used as intermediates. It undergoes Sharpless kinetic resolution and ring-closing metathesis to yield nine membered oxocene.

Bemerkungen

Keep away from heat. Incompatible with Oxidizing agents.

Literaturverweise

Michael T Crimmins; Mark T Powell. Enantioselective total synthesis of (+)-obtusenyne.Journal of the American Chemical Society.2003, 125 (25), 7592-7595.

Thomas W. Gibson; William F. Erman. Photochemistry of substituted 1,5-hexadien-3-ones.J. Org. Chem.1972, 37 (8), 1148-1154.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H226

Flammable liquid and vapour.

Sicherheitshinweise: P210-P261

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray.

Weitere Referenzen

Beilstein
1719962
Gefahrenklasse
3
Verpackungsgruppe
III
Harmonized Tariff Code
2905.29
TSCA
No

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