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603-32-7 - Triphenylarsine, 97% - L03616 - Alfa Aesar

L03616 Triphenylarsine, 97%

CAS-Nummer
603-32-7
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 32,96
25g 123,60
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Triphenylarsine, 97%

MDL
MFCD00002994
EINECS
210-032-9

Chemische Eigenschaften

Formel
C18H15As
Molmasse
306.24
Schmelzpunkt
58-62°
Siedepunkt
360°
Flammpunkt
265°(509°F)
Löslichkeit
Soluble in methanol. Insoluble in water.

Anwendungen

Triphenylarsine is used in certain metal-catalyzed coupling reactions. It is a precursor to tetraphenylarsonium chloride a popular precipitating agent.

Bemerkungen

Handle and store under inert gas. Incompatible materials are Strong oxidizing agents.

Literaturverweise

Raj K. Poddar; I.P. Khullar; Umesh Agarwala. Some ruthenium(III) complexes with triphenylarsine.Inorganic and Nuclear Chemistry Letters.1974, 10 221-227.

Clifford R. Kistner; Jon D. Blackman; William C. Harris. Preparation and properties of some triphenylarsine- and triphenyl-stibine-stabilized organoplatinum(II) compounds.Inorg. Chem.1969, 8 (10), 2165-2167.

Can be cleaved to sodium diphenylarsenide by Na metal. A mole of PhNa is also produced, but can be selectively destroyed by protonation with NH4Br: Chem. Ber., 100, 1230 (1967). For use in the preparation of chelating ligands, see: Synthesis, 350 (1979). Similarly, Li metal gives Li diphenylarsenide: J. Org. Chem., 32, 2627 (1967). For a review of the chemistry of metal arsenides, see: Synthesis, 328 (1974).

Preferred to phosphines as a ligand in certain metal-catalyzed coupling reactions, e.g. in the Pd catalyzed Stille coupling of aryl stannanes with aryl halides: Tetrahedron Lett., 36, 2191 (1995), of silylated allylic stannanes with alkyl halides: J. Org. Chem., 60, 4647 (1995), the Pd catalyzed homocoupling of organostannanes: Synth. Commun., 27, 641 (1997), the Pd catalyzed coupling of aryl- or alkynylzinc chlorides with alkenyl halides: Synlett, 344 (1995), or the Suzuki coupling of arylboronic acids with sensitive halides: Org. Synth., 75, 69 (1997).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H331-H400-H410

Toxic if swallowed. Toxic if inhaled. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Sicherheitshinweise: P261-P273-P264-P301+P310-P304+P340-P311-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wash thoroughly after handling. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1842037
Gefahrenklasse
6.1
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
CH7942500

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